Synthesis and Site-selective Metalation of a Benzene-o-dithiol/ Pyridylimine Ligand
نویسندگان
چکیده
The benzene-o-dithiol/pyridylimine (S-S)/(N-N) ligand H2-7, representing the first example of a new type of bis(bidentate) heterodonor ligands with a mixed donor set, has been synthesized by Schiff base condensation of pyridine-2-carbaldehyde with an amine-substituted benzene-o-dithiol moiety. Bis(cyclopentadienyl)titanium dichloride reacts selectively at the S-S donor group of H2-7 to yield complex [Cp2Ti(7)].
منابع مشابه
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